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Phenomenon of Sulphur cycle

a) Decomposition of larger, organic sulphur compounds to smaller units:

Sulphate is assimilated by plants in sulphur containing amino acids & then proteins. Degradation of proteins (proteolysis) liberates amino acids e.g. Methionine & cysteine. From these amino acids H2S is liberated by microbes e.g. Pseudomonas spp. & Flavobacterium spp.

Reaction:

Proteins →Amino acids →Pyruvic acid, H2S & ammonia.

 

b) Oxidation of H2S into sulphur elements:

H2S produced from sulphate reduction & amino acid decomposition is oxidized to elemental sulphur. It occurs in the presence of photosynthetic sulphur bacteria

Carbon-dioxide +2 H2S —Eight chromatium—> (CH2O)6 + H2O + 2S

  1. Chlorobium
  2. Rhodospirillium
  3. Rhodopseudomonas

 

b. Oxidation of elemental sulphur to sulphates:

Thiobacillus thioxidants oxidizes sulphur to sulphates.

2S +2 H2O +3O2 Microbes   2 H2SO4

Sulphate is assimilated by plants.

Assimilation: To Produce any substance from any substance.

Sulphate is assimilated by plants & is used in the formation of sulphur containing amino acids (cysteine & methionine) & then into proteins.

 

c. Reduction of sulphates:

Desulphotomaculum reduces sulphate into H2S

4H + CaSO4→ H2S + Ca(OH)2 + 2 H2O

 

 

Reduction by microbes:

  1. Desulphovibrio spp.
  2. Bacillus spp.
  3. Pseudomonas spp.
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